Behold! A great wall of links for fledgling and veteran Roleplayers alike!
Canon Puncture is a show that covers a little bit of everything in terms of RPG
One Shot Podcast: Backstory with Alex Roberts features backstory interview
The GamersTable Podcast covers the gamut of real people talking about RPG’s
The Play Better podcast focuses on improving play
One Shot Podcast: One Shot features One Shot run throughs of Roleplaying Games.
One Shot Podcast: First Watch and Second Watch
One Shot Podcast: Campaign features campaign play of Roleplaying Games
System Mastery covers a wide range of Roleplaying Games
RPG Podcasts contains some duplicates from above but also collects a wider range of podcasts.
Happy Jacks contains actual play Roleplaying Games and the like